PayPal NVP CURL connection error #60: SSL certificate problem: unable to get local issuer certificate
So, you can solve the problem by disabling the «PayPal Express Checkout» → «Basic Settings - PayPal Express Checkout» → «Advanced Settings» → «Enable SSL verification» option or «PayPal Website Payments Standard» → «Basic Settings - PayPal Website Payments Standard» → «Advanced Settings» → «Enable SSL verification» option.
A better solution: How to fix the «SSL certificate problem: unable to get local issuer certificate» issue.